Technical guide · 2026-08-14

Molybdenum Alloys

Molybdenum combines high-temperature stiffness with lower density than tungsten, while TZM and lanthanum-doped systems improve recrystallization or creep behavior only when processing and grain structure are controlled.

01

Definition and boundary

Includes pure Mo, TZM and Mo-La; excludes molybdenum-bearing steel and nickel alloys.

Reference information only: final acceptance is controlled by the ordered product specification, condition, dimensions and certified test results.

02

How the material system works

01

Mo retains stiffness at heat.

02

Ti-Zr carbides strengthen TZM.

03

Lanthanum oxide stabilizes elongated grains.

03

Representative grades and systems

Grade or systemSelection focusQualification
Pure molybdenumGeneral vacuum/inert high-temperature product.Confirm the governing product specification, delivery condition, section size and acceptance tests before treating designations as interchangeable.
TZMMo-Ti-Zr-C strengthened alloy.Confirm the governing product specification, delivery condition, section size and acceptance tests before treating designations as interchangeable.
Mo-LaOxide-dispersed recrystallization-resistant system.Confirm the governing product specification, delivery condition, section size and acceptance tests before treating designations as interchangeable.

04

Properties and trade-offs

01

Hot stiffness

02

Low thermal expansion

03

Rapid oxidation in air at elevated temperature

05

Product forms and supply conditions

Sheet, plate or foilBar, rod or wirePowder-metallurgy or fabricated component

06

Applications and selection

Applications and selection

  • Vacuum furnace parts
  • Glass-melting electrodes
  • Semiconductor hardware

Properties and trade-offs

  • Define atmosphere first.
  • Use TZM for load, not generic oxidation resistance.
  • Specify grain direction for formed parts.

07

Fabrication, durability and inspection

01

Protect from oxidizing heat.

02

Use large bend radii by condition.

03

Qualify electron-beam, laser or brazed joints.

08

Procurement checklist

  • State pure Mo, TZM or Mo-La.
  • Define stress-relieved/recrystallized condition.
  • Specify O/C impurities, grain direction and surface.
Discuss a material requirement

09

Standards, sources and review

Standards and designation context

  • Applicable ASTM B10 product specification
  • Buyer drawing and material condition
  • Qualified joining and inspection procedure

Authoritative research sources